发信人: walking (一棵行走的树), 信区: S_Chemistry
标 题: 王新平老师再发jacs一篇
发信站: 南京大学小百合站 (Tue Jul 1 02:30:39 2014)
A Crystalline Phosphaalkene Radical Anion
Xiaobo Pan , Xingyong Wang , Yue Zhao , Yunxia Sui,and Xinping Wang
J. Am. Chem. Soc., Just Accepted Manuscript
DOI: 10.1021/ja504001x
Publication Date (Web): June 30, 2014
Copyright © 2014 American Chemical Society
Abstract
Salts containing phosphaalkene radical anions have been isolated and
characterized by electron paramagnetic resonance (EPR) spectroscopy, UV-vis
absorption spectroscopy and single crystal X-ray diffraction. The radical
anions feature elongated P–C bonds compared to the neutral phosphaalkene.
Their EPR spectra and theoretical calculations indicate the spin density of
the radicals mainly resides on phosphorus atoms. The work provides the first
example of a crystalline phosphaalkene radical anion.
http://pubs.acs.org/doi/abs/10.1021/ja504001x
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※ 来源:．南京大学小百合站 http://bbs.nju.edu.cn [FROM: 152.135.235.188]
标 题: 王新平老师再发jacs一篇
发信站: 南京大学小百合站 (Tue Jul 1 02:30:39 2014)
A Crystalline Phosphaalkene Radical Anion
Xiaobo Pan , Xingyong Wang , Yue Zhao , Yunxia Sui,and Xinping Wang
J. Am. Chem. Soc., Just Accepted Manuscript
DOI: 10.1021/ja504001x
Publication Date (Web): June 30, 2014
Copyright © 2014 American Chemical Society
Abstract
Salts containing phosphaalkene radical anions have been isolated and
characterized by electron paramagnetic resonance (EPR) spectroscopy, UV-vis
absorption spectroscopy and single crystal X-ray diffraction. The radical
anions feature elongated P–C bonds compared to the neutral phosphaalkene.
Their EPR spectra and theoretical calculations indicate the spin density of
the radicals mainly resides on phosphorus atoms. The work provides the first
example of a crystalline phosphaalkene radical anion.
http://pubs.acs.org/doi/abs/10.1021/ja504001x
--
※ 来源:．南京大学小百合站 http://bbs.nju.edu.cn [FROM: 152.135.235.188]
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