发信人: vonhabsburg (HRH The Duke of Aled KG GCB OM GCVO FRS), 信区: S_Chemistry
标 题: 疯了！又一篇JACS！
发信站: 南京大学小百合站 (Thu Feb 21 02:46:34 2013)
Salts containing triarylphosphine radical cations 1•+ and 2•+ have been
isolated and characterized by EPR and UV-vis absorption spectroscopy, as well
as single-crystal X-ray diffraction. Radical 1•+ exhibits a relaxed pyramidal
geometry while radicals of 2•+ become fully planar. EPR studies and
theoretical calculations show the introduction of the bulky aryl groups leads
to enhanced p-character of the SOMO and radicals become less pyramidalized or
fully flattened.
--
※ 来源:．南京大学小百合站 http://bbs.nju.edu.cn [FROM: 129.67.119.178]
标 题: 疯了！又一篇JACS！
发信站: 南京大学小百合站 (Thu Feb 21 02:46:34 2013)
Salts containing triarylphosphine radical cations 1•+ and 2•+ have been
isolated and characterized by EPR and UV-vis absorption spectroscopy, as well
as single-crystal X-ray diffraction. Radical 1•+ exhibits a relaxed pyramidal
geometry while radicals of 2•+ become fully planar. EPR studies and
theoretical calculations show the introduction of the bulky aryl groups leads
to enhanced p-character of the SOMO and radicals become less pyramidalized or
fully flattened.
--
※ 来源:．南京大学小百合站 http://bbs.nju.edu.cn [FROM: 129.67.119.178]
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